In the ethene/CO copolymerization catalyzed by palladium derivatives, species arising from ethene insertion into the palladium-acyl bond have been shown to play a key role. We report here the synthesis, spectroscopic characterization, and X-ray structure of the complex [Pd{CH2CH2C(O)Me}(HL)][BAr ' (4)] (HL = 6-Me-2,2 ' -bipyridine, Ar ' = 3,5-(CF3)(2)C6H3), 4, the first one having an ancillary N,N ligand to be characterized in the solid state.
In the ethene/CO copolymerization catalyzed by palladium derivatives, species arising from ethene insertion into the palladium-acyl bond have been shown to play a key role. We report here the synthesis, spectroscopic characterization, and X-ray structure of the complex [Pd{CH2CH2C(O)Me}(HL)][BAr¢4] (HL ) 6-Me- 2,2¢-bipyridine, Ar¢ ) 3,5-(CF3)2C6H3), 4, the first one having an ancillary N,N ligand to be characterized in the solid state.
Synthesis and molecular structure of [Pd{CH2CH2C(O)Me}(HL)][BAr '(4)] (HL=6-Me-2,2 '-bipyridine, Ar '=3,5-(CF3)(2)C6H3), an intermediate relevant to ethene/CO copolymerization / Stoccoro, S; Minghetti, G; Cinellu, Maria Agostina; Zucca, Antonio; Manassero, M.. - In: ORGANOMETALLICS. - ISSN 0276-7333. - 20:19(2001), pp. 4111-4113. [10.1021/om010278f]
Synthesis and molecular structure of [Pd{CH2CH2C(O)Me}(HL)][BAr '(4)] (HL=6-Me-2,2 '-bipyridine, Ar '=3,5-(CF3)(2)C6H3), an intermediate relevant to ethene/CO copolymerization
Stoccoro S;CINELLU, Maria Agostina;ZUCCA, Antonio;
2001
Abstract
In the ethene/CO copolymerization catalyzed by palladium derivatives, species arising from ethene insertion into the palladium-acyl bond have been shown to play a key role. We report here the synthesis, spectroscopic characterization, and X-ray structure of the complex [Pd{CH2CH2C(O)Me}(HL)][BAr ' (4)] (HL = 6-Me-2,2 ' -bipyridine, Ar ' = 3,5-(CF3)(2)C6H3), 4, the first one having an ancillary N,N ligand to be characterized in the solid state.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
