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EnglishIn the ethene/CO copolymerization catalyzed by palladium derivatives, species arising from ethene insertion into the palladium-acyl bond have been shown to play a key role. We report here the synthesis, spectroscopic characterization, and X-ray structure of the complex [Pd{CH2CH2C(O)Me}(HL)][BAr ' (4)] (HL = 6-Me-2,2 ' -bipyridine, Ar ' = 3,5-(CF3)(2)C6H3), 4, the first one having an ancillary N,N ligand to be characterized in the solid state.
In the ethene/CO copolymerization catalyzed by palladium derivatives, species arising from ethene insertion into the palladium-acyl bond have been shown to play a key role. We report here the synthesis, spectroscopic characterization, and X-ray structure of the complex [Pd{CH2CH2C(O)Me}(HL)][BAr¢4] (HL ) 6-Me- 2,2¢-bipyridine, Ar¢ ) 3,5-(CF3)2C6H3), 4, the first one having an ancillary N,N ligand to be characterized in the solid state.
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| Titolo: | Synthesis and molecular structure of [Pd{CH2CH2C(O)Me}(HL)][BAr '(4)] (HL=6-Me-2,2 '-bipyridine, Ar '=3,5-(CF3)(2)C6H3), an intermediate relevant to ethene/CO copolymerization |
| Autori: | |
| Data di pubblicazione: | 2001 |
| Rivista: | |
| Abstract: | In the ethene/CO copolymerization catalyzed by palladium derivatives, species arising from ethene insertion into the palladium-acyl bond have been shown to play a key role. We report here the synthesis, spectroscopic characterization, and X-ray structure of the complex [Pd{CH2CH2C(O)Me}(HL)][BAr ' (4)] (HL = 6-Me-2,2 ' -bipyridine, Ar ' = 3,5-(CF3)(2)C6H3), 4, the first one having an ancillary N,N ligand to be characterized in the solid state. |
| Handle: | http://hdl.handle.net/11388/84919 |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
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