An auraoxetane, obtained from the reaction of norbornene with a gold(III) oxo complex, has been isolated and fully characterized (see structure). Action of the olefin leads to elimination of the epoxide from the auraoxetane. An auraoxetane, obtained from the reaction of norbornene with a gold(III) oxo complex, has been isolated and fully characterized (see structure). Action of the olefin leads to elimination of the epoxide from the auraoxetane.
Reactions of Gold(III) Oxo Complexes with Cyclic Alkenes / Cinellu, Maria Agostina; Minghetti, G; Cocco, T; Stoccoro, S; Zucca, Antonio; Manassero, M.. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 44:42(2005), pp. 6892-6895. [10.1002/anie.200501754]
Reactions of Gold(III) Oxo Complexes with Cyclic Alkenes
CINELLU, Maria Agostina;Stoccoro, S;ZUCCA, Antonio;
2005-01-01
Abstract
An auraoxetane, obtained from the reaction of norbornene with a gold(III) oxo complex, has been isolated and fully characterized (see structure). Action of the olefin leads to elimination of the epoxide from the auraoxetane. An auraoxetane, obtained from the reaction of norbornene with a gold(III) oxo complex, has been isolated and fully characterized (see structure). Action of the olefin leads to elimination of the epoxide from the auraoxetane.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
