Unusual platinum(II) trimetalated derivatives have been synthesized and characterized by reaction of cis-[Pt(R)(2)(DMSO)(2)] (R = Me, Ph) and 6-phenyl-2,2'-bipyridine. The behavior of the substituted 2,2'-bipyridine as a threefold-deprotonated ligand is unprecedented.

Unusual platinum(II) trimetalated derivatives have been synthesized and characterized by reaction of cis-[Pt(R)2(DMSO)2] (R ) Me, Ph) and 6-phenyl-2,2¢- bipyridine. The behavior of the substituted 2,2¢-bipyridine as a threefold-deprotonated ligand is unprecedented.

Multiple C-H bond activation. 3-fold deprotonated 6-phenyl-2,2’-bipyridine as a bridging ligand in dinuclear platinum(II) derivatives / Zucca, Antonio; Doppiu, A; Cinellu, Maria Agostina; Stoccoro, Sergio; Minghetti, G; Manassero, M.. - In: ORGANOMETALLICS. - ISSN 0276-7333. - 21:5(2002), pp. 783-785. [10.1021/om010913h]

Multiple C-H bond activation. 3-fold deprotonated 6-phenyl-2,2’-bipyridine as a bridging ligand in dinuclear platinum(II) derivatives

ZUCCA, Antonio;CINELLU, Maria Agostina;STOCCORO, Sergio;
2002-01-01

Abstract

Unusual platinum(II) trimetalated derivatives have been synthesized and characterized by reaction of cis-[Pt(R)2(DMSO)2] (R ) Me, Ph) and 6-phenyl-2,2¢- bipyridine. The behavior of the substituted 2,2¢-bipyridine as a threefold-deprotonated ligand is unprecedented.
2002
Unusual platinum(II) trimetalated derivatives have been synthesized and characterized by reaction of cis-[Pt(R)(2)(DMSO)(2)] (R = Me, Ph) and 6-phenyl-2,2'-bipyridine. The behavior of the substituted 2,2'-bipyridine as a threefold-deprotonated ligand is unprecedented.
Multiple C-H bond activation. 3-fold deprotonated 6-phenyl-2,2’-bipyridine as a bridging ligand in dinuclear platinum(II) derivatives / Zucca, Antonio; Doppiu, A; Cinellu, Maria Agostina; Stoccoro, Sergio; Minghetti, G; Manassero, M.. - In: ORGANOMETALLICS. - ISSN 0276-7333. - 21:5(2002), pp. 783-785. [10.1021/om010913h]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11388/84472
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