Aromatic and aliphatic aldehydes are simply converted into esters by an efficient oxidative esterification carried out under mild conditions. The aldehydes are converted in situ into their corresponding acyl chlorides, which are then reacted with primary and secondary aliphatic, benzylic, allylic, and propargylic alcohols and phenols. A variety of esters are obtained in high yields.
Metal-Free Direct Oxidation of Aldehydes to Esters Using TCCA / Gaspa, S; Porcheddu, Andrea; DE LUCA, Lidia Vera Giovanna. - In: ORGANIC LETTERS. - ISSN 1523-7060. - 17:15(2015), pp. 3666-3669. [10.1021/acs.orglett.5b01579]
Metal-Free Direct Oxidation of Aldehydes to Esters Using TCCA
Gaspa S;PORCHEDDU, Andrea;DE LUCA, Lidia Vera Giovanna
2015-01-01
Abstract
Aromatic and aliphatic aldehydes are simply converted into esters by an efficient oxidative esterification carried out under mild conditions. The aldehydes are converted in situ into their corresponding acyl chlorides, which are then reacted with primary and secondary aliphatic, benzylic, allylic, and propargylic alcohols and phenols. A variety of esters are obtained in high yields.File in questo prodotto:
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