Treatment of 6,6′-dimethoxy-2,2′-bipyridine (bipy 2OMe) with gold(III) acetate results in the exclusive formation of a cyclometalated gold(III) derivative arising from activation of the C(3) - H bond of a pyridine ring.
Intramolecular C(sp2)-H Bond Activation in 6,6'-Dimethoxy-2,2'-Bipyridine with Gold(III). Crystal and Molecular Structure of the First N',C(3) “Rollover” Cycloaurated Derivative / Cocco, Fabio; Cinellu, Maria Agostina; Minghetti, G; Zucca, Antonio; Stoccoro, Sergio; Maiore, Laura; Manassero, M.. - In: ORGANOMETALLICS. - ISSN 0276-7333. - 29:5(2010), pp. 1064-1066. [10.1021/om1000474]
Intramolecular C(sp2)-H Bond Activation in 6,6'-Dimethoxy-2,2'-Bipyridine with Gold(III). Crystal and Molecular Structure of the First N',C(3) “Rollover” Cycloaurated Derivative
COCCO, Fabio;CINELLU, Maria Agostina;ZUCCA, Antonio;STOCCORO, Sergio;MAIORE, Laura;
2010-01-01
Abstract
Treatment of 6,6′-dimethoxy-2,2′-bipyridine (bipy 2OMe) with gold(III) acetate results in the exclusive formation of a cyclometalated gold(III) derivative arising from activation of the C(3) - H bond of a pyridine ring.File in questo prodotto:
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