Treatment of 6,6′-dimethoxy-2,2′-bipyridine (bipy 2OMe) with gold(III) acetate results in the exclusive formation of a cyclometalated gold(III) derivative arising from activation of the C(3) - H bond of a pyridine ring.

Intramolecular C(sp2)-H Bond Activation in 6,6'-Dimethoxy-2,2'-Bipyridine with Gold(III). Crystal and Molecular Structure of the First N',C(3) “Rollover” Cycloaurated Derivative / Cocco, Fabio; Cinellu, Maria Agostina; Minghetti, G; Zucca, Antonio; Stoccoro, Sergio; Maiore, Laura; Manassero, M.. - In: ORGANOMETALLICS. - ISSN 0276-7333. - 29:5(2010), pp. 1064-1066. [10.1021/om1000474]

Intramolecular C(sp2)-H Bond Activation in 6,6'-Dimethoxy-2,2'-Bipyridine with Gold(III). Crystal and Molecular Structure of the First N',C(3) “Rollover” Cycloaurated Derivative

COCCO, Fabio;CINELLU, Maria Agostina;ZUCCA, Antonio;STOCCORO, Sergio;MAIORE, Laura;
2010

Abstract

Treatment of 6,6′-dimethoxy-2,2′-bipyridine (bipy 2OMe) with gold(III) acetate results in the exclusive formation of a cyclometalated gold(III) derivative arising from activation of the C(3) - H bond of a pyridine ring.
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11388/62564
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 44
  • ???jsp.display-item.citation.isi??? 44
social impact