The reaction of ferriohydridosilanes Cp(CO)(L)Fe - SiR2H (R = Me, t-Bu, Ph, o-Tolyl; L = CO, Ph3P) 1a-e with dimethyldioxirane (as an acetone solution) leads directly to the corresponding ferriosilanols Cp(CO)(L)Fe-SiR2OH 2a-e in moderate to excellent yields
Conversion of Ferriosilanes to Ferriosilanols by Selective Oxidation of the SiH Function by Dimethyldioxirane / W., Adam; Azzena, Ugo Gavino; F., Prechtl; K., Hindahl; W., Malisch. - In: CHEMISCHE BERICHTE-RECUEIL. - ISSN 0009-2940. - 125:(1992), pp. 1409-1411. [10.1002/cber.19921250618]
Conversion of Ferriosilanes to Ferriosilanols by Selective Oxidation of the SiH Function by Dimethyldioxirane
AZZENA, Ugo Gavino;
1992-01-01
Abstract
The reaction of ferriohydridosilanes Cp(CO)(L)Fe - SiR2H (R = Me, t-Bu, Ph, o-Tolyl; L = CO, Ph3P) 1a-e with dimethyldioxirane (as an acetone solution) leads directly to the corresponding ferriosilanols Cp(CO)(L)Fe-SiR2OH 2a-e in moderate to excellent yieldsFile in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
