An easy reversible switching of the electronic ground state in a pentacoordinated copper(II) complex is reported for the first time. The simple protonation of a carboxylic group in a Cu(II) complex with a {d(x2-y2)}(1) electronic configuration leads to a flip of the ground electronic configuration from {d(x2-y2)}(1) to {d(z2)}(1) in the metal ion.

Reversible switching of the electronic ground state in a pentacoordinated Cu(II) complex / A., Sasmal; S., Saha; C. J., Gómez García; C., Desplanches; Garribba, Eugenio; A., Bauzá; A., Frontera; R., Scott; R. J., Butcherf; S., Mitr. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 49:(2013), pp. 7806-7808. [10.1039/c3cc44276d]

Reversible switching of the electronic ground state in a pentacoordinated Cu(II) complex

GARRIBBA, Eugenio;
2013-01-01

Abstract

An easy reversible switching of the electronic ground state in a pentacoordinated copper(II) complex is reported for the first time. The simple protonation of a carboxylic group in a Cu(II) complex with a {d(x2-y2)}(1) electronic configuration leads to a flip of the ground electronic configuration from {d(x2-y2)}(1) to {d(z2)}(1) in the metal ion.
2013
Reversible switching of the electronic ground state in a pentacoordinated Cu(II) complex / A., Sasmal; S., Saha; C. J., Gómez García; C., Desplanches; Garribba, Eugenio; A., Bauzá; A., Frontera; R., Scott; R. J., Butcherf; S., Mitr. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 49:(2013), pp. 7806-7808. [10.1039/c3cc44276d]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11388/59163
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