Mononuclear amidogold(III) complexes [Au(C,N,N)(NRR')]-[PF6] [C,N,N = N2C10H7(CMe2C6H4)-6, where N2C10H8 = 2,2'-bipy; R H, R' = p-tolyl (5), o-xylyl (6), isobutyl (7), sec-butyl (8), R R' = Et (9)], [Au(C,N)(AcO)(NHC6H4NO2-4)] (10) [C,N = NC5H4(CH2C6H4)-2, where NC5H5 = py] and [Au(N,N)(NHC6H4NO2-4)(2)][PF6] (11) (N,N = 2,2'-bipy), have been synthesized in fairly good yields by reaction of the hydroxo, methoxo, or acetato complexes 1-4 [[Au(C,N,N)-(OR)][PF6] [R = H (1), Me (2)], [Au(C,N)(ACO)(2)] (3), [Au-(N,N)(OH)(2)][PF6] (4)) with amines. The structure of [Au(C,N,N)(NHC6H3Me2-2,6)][PF6] (6) has been determined by X-ray diffraction. Reaction of the hydroxo complex 4 with NH2C6H4Me-4 gives metallic gold, the protonated ligand [N,NH][PF6] and organic products, the main one being azotoluene.

Synthesis and characterization of mononuclear amidogold(III) complexes - Crystal structure of [Au(N2C10H7(CMe2C6H4)-6](NHC6H3Me2-2,6)][PF6] - Oxidation of 4-methylaniline to azotoluene RID D-3096-2011 / Cinellu, Maria Agostina; Minghetti, G; Pinna, Mv; Stoccoro, Sergio; Zucca, Antonio; Manassero, M.. - In: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. - ISSN 1434-1948. - 12(2003), pp. 2304-2310. [10.1002/ejic.200200377]

Synthesis and characterization of mononuclear amidogold(III) complexes - Crystal structure of [Au(N2C10H7(CMe2C6H4)-6](NHC6H3Me2-2,6)][PF6] - Oxidation of 4-methylaniline to azotoluene RID D-3096-2011

CINELLU, Maria Agostina;Pinna, MV;STOCCORO, Sergio;ZUCCA, Antonio;
2003

Abstract

Mononuclear amidogold(III) complexes [Au(C,N,N)(NRR')]-[PF6] [C,N,N = N2C10H7(CMe2C6H4)-6, where N2C10H8 = 2,2'-bipy; R H, R' = p-tolyl (5), o-xylyl (6), isobutyl (7), sec-butyl (8), R R' = Et (9)], [Au(C,N)(AcO)(NHC6H4NO2-4)] (10) [C,N = NC5H4(CH2C6H4)-2, where NC5H5 = py] and [Au(N,N)(NHC6H4NO2-4)(2)][PF6] (11) (N,N = 2,2'-bipy), have been synthesized in fairly good yields by reaction of the hydroxo, methoxo, or acetato complexes 1-4 [[Au(C,N,N)-(OR)][PF6] [R = H (1), Me (2)], [Au(C,N)(ACO)(2)] (3), [Au-(N,N)(OH)(2)][PF6] (4)) with amines. The structure of [Au(C,N,N)(NHC6H3Me2-2,6)][PF6] (6) has been determined by X-ray diffraction. Reaction of the hydroxo complex 4 with NH2C6H4Me-4 gives metallic gold, the protonated ligand [N,NH][PF6] and organic products, the main one being azotoluene.
Synthesis and characterization of mononuclear amidogold(III) complexes - Crystal structure of [Au(N2C10H7(CMe2C6H4)-6](NHC6H3Me2-2,6)][PF6] - Oxidation of 4-methylaniline to azotoluene RID D-3096-2011 / Cinellu, Maria Agostina; Minghetti, G; Pinna, Mv; Stoccoro, Sergio; Zucca, Antonio; Manassero, M.. - In: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. - ISSN 1434-1948. - 12(2003), pp. 2304-2310. [10.1002/ejic.200200377]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11388/49816
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