A new hydrazone derivative, di-2-pyridyl ketone [phenyl(semicarbazono)acetyl]hydrazone (H-2L), has been prepared and examined as a chelating agent towards metal ions. The molecular structure of the copper complex [CuLCl2].H2O consists of a pair of structurally distinct metal centres with different environments bound to the heptadentate hydrazonic ligand and held together by a -N-N- bridge.

A NEW POLYDENTATE HYDRAZONIC LIGAND AND ITS DINUCLEAR COPPER(II) COMPLEX WITH DIFFERENT COORDINATION ENVIRONMENTS / Bacchi, A., Battaglia, L.p., Carcelli, M., Pelizzi, C., Pelizzi, G., Solinas, C., Zoroddu, M.A.. - In: JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS. - ISSN 0300-9246. - 5(1993), pp. 775-779. [10.1039/dt9930000775]

A NEW POLYDENTATE HYDRAZONIC LIGAND AND ITS DINUCLEAR COPPER(II) COMPLEX WITH DIFFERENT COORDINATION ENVIRONMENTS

SOLINAS, Costantino;ZORODDU, Maria Antonietta
1993-01-01

Abstract

A new hydrazone derivative, di-2-pyridyl ketone [phenyl(semicarbazono)acetyl]hydrazone (H-2L), has been prepared and examined as a chelating agent towards metal ions. The molecular structure of the copper complex [CuLCl2].H2O consists of a pair of structurally distinct metal centres with different environments bound to the heptadentate hydrazonic ligand and held together by a -N-N- bridge.
1993
A NEW POLYDENTATE HYDRAZONIC LIGAND AND ITS DINUCLEAR COPPER(II) COMPLEX WITH DIFFERENT COORDINATION ENVIRONMENTS / Bacchi, A., Battaglia, L.p., Carcelli, M., Pelizzi, C., Pelizzi, G., Solinas, C., Zoroddu, M.A.. - In: JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS. - ISSN 0300-9246. - 5(1993), pp. 775-779. [10.1039/dt9930000775]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11388/49527
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