The reaction of CuCl2·2H2O with trimethoprim in a methanolic solution affords the [CUCl(μ-OCH3)(trimethoprim)]2 dimeric complex (1) which has been characterized by single crystal X-ray diffraction. Compound 1 is monoclinic, space group P21/n with a=12.091(2), b=7.647(3), c=19.815(5) Å, β=96.63(2)°, Z=2, R=0.044, Rw=0.047 for 1562 observed reflections with I>2σ(I). The two copper atoms are held together by methoxo bridges and coordinate one terminal chlorine atom and one trimethoprim ligand each, the latter behaving as a monodentate ligand through a pyrimidinic nitrogen atom. © 1990.

Metal complexes of 2,4-diamino-5-(3′,4′,5′-trimethoxybenzyl)pyrimidine (trimethoprim) Part IV. Synthesis and X-ray structure of [CuCl(μ-OCH3)(trimethoprim)]2 / Demartin, F; Manassero, M; Naldini, L; Panzanelli, Angelo; Zoroddu, Maria Antonietta. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - 171:2(1990), pp. 229-233. [10.1016/S0020-1693(00)80437-5]

Metal complexes of 2,4-diamino-5-(3′,4′,5′-trimethoxybenzyl)pyrimidine (trimethoprim) Part IV. Synthesis and X-ray structure of [CuCl(μ-OCH3)(trimethoprim)]2

PANZANELLI, Angelo;ZORODDU, Maria Antonietta
1990

Abstract

The reaction of CuCl2·2H2O with trimethoprim in a methanolic solution affords the [CUCl(μ-OCH3)(trimethoprim)]2 dimeric complex (1) which has been characterized by single crystal X-ray diffraction. Compound 1 is monoclinic, space group P21/n with a=12.091(2), b=7.647(3), c=19.815(5) Å, β=96.63(2)°, Z=2, R=0.044, Rw=0.047 for 1562 observed reflections with I>2σ(I). The two copper atoms are held together by methoxo bridges and coordinate one terminal chlorine atom and one trimethoprim ligand each, the latter behaving as a monodentate ligand through a pyrimidinic nitrogen atom. © 1990.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11388/48939
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