The reductive cleavage of diarylmethyl methyl ethers with Li metal in THF led to quantitative formation of the corresponding diarylmethyl anions. Quenching with electrophiles afforded substituted diarylmethanes in good to excellent yields
Single and Double Reductive Cleavage of C-O Bonds of Aromatic Acetals and Ketals: Generation of Benzylic Mono- and Dicarbanions / Azzena, U.G., G., M., Pisano, L., B., S.. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 35:36(1994), pp. 6759-6762. [10.1016/S0040-4039(00)73488-5]
Single and Double Reductive Cleavage of C-O Bonds of Aromatic Acetals and Ketals: Generation of Benzylic Mono- and Dicarbanions
AZZENA, Ugo Gavino;PISANO, Luisa;
1994-01-01
Abstract
The reductive cleavage of diarylmethyl methyl ethers with Li metal in THF led to quantitative formation of the corresponding diarylmethyl anions. Quenching with electrophiles afforded substituted diarylmethanes in good to excellent yieldsFile in questo prodotto:
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