Selectivity between the two double bonds of the title compound was observed for a number of reagents. For example, cycloaddition with cyclopentadiene and anthracene, as well as reduction with molecular hydrogen (uder Pd catalysis), took place at the unsubstitued double bond, while cyclohexadiene and alfa terpinene gave (uncatalyzed) reduction at the more substituted double bond.
Dichotomy in the Double Bond Reactivity of 2,3-Bis(phenylsulphonyl)bicyclo-(2.2.1)hepta-2,5-diene and Related Compounds / Azzena, Ugo Gavino; S., Cossu; O., De Lucchi; G., Melloni. - In: GAZZETTA CHIMICA ITALIANA. - ISSN 0016-5603. - 119:(1989), pp. 357-358.
Dichotomy in the Double Bond Reactivity of 2,3-Bis(phenylsulphonyl)bicyclo-(2.2.1)hepta-2,5-diene and Related Compounds
AZZENA, Ugo Gavino;
1989-01-01
Abstract
Selectivity between the two double bonds of the title compound was observed for a number of reagents. For example, cycloaddition with cyclopentadiene and anthracene, as well as reduction with molecular hydrogen (uder Pd catalysis), took place at the unsubstitued double bond, while cyclohexadiene and alfa terpinene gave (uncatalyzed) reduction at the more substituted double bond.File in questo prodotto:
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