Cyanometallates [N(PPh3)2][Ag(CN)2] 1 and [N(PPh3)2]2[Pd(CN)4] 2 reacted with SnPh3Cl, producing anionic complexes characterized by IR and Sn-119 NMR spectroscopy, an X-ray structural analysis of the silver complex evidencing a Sn-NC-Ag bridging interaction; the crystal structure of 1 has also been determined for comparison.
EASY ACCESS TO A NEW CLASS OF ANIONIC CYANO-BRIDGED DINUCLEAR AND TRINUCLEAR ORGANOTIN ADDUCTS - CRYSTAL-STRUCTURE OF [N(PPH3)2][CLPH3SN(MU-NC)AG(CN)] / Carcelli, M; Ferrari, C; Pelizzi, C; Pelizzi, G; Predieri, G; Solinas, Costantino. - In: JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS. - ISSN 0300-9246. - 13(1992), pp. 2127-2128. [10.1039/dt9920002127]
EASY ACCESS TO A NEW CLASS OF ANIONIC CYANO-BRIDGED DINUCLEAR AND TRINUCLEAR ORGANOTIN ADDUCTS - CRYSTAL-STRUCTURE OF [N(PPH3)2][CLPH3SN(MU-NC)AG(CN)]
SOLINAS, Costantino
1992-01-01
Abstract
Cyanometallates [N(PPh3)2][Ag(CN)2] 1 and [N(PPh3)2]2[Pd(CN)4] 2 reacted with SnPh3Cl, producing anionic complexes characterized by IR and Sn-119 NMR spectroscopy, an X-ray structural analysis of the silver complex evidencing a Sn-NC-Ag bridging interaction; the crystal structure of 1 has also been determined for comparison.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
