The cathodic reduction of the complexes [LPtCl] and [LPtL′] (BF4) [HL 6-(1-methylbenzyl)-2,2′-bipyridine and L′ triphenylphosphine, pyridine, or acetonitrile] has been studied in acetonitrile and dichloromethane solvents. The main goal has been that of defining the nature and reactivity of the corresponding relatively stable one-electron reduced forms. In particular, X-band EPR spectrometry has allowed us to get information about the character (metal- or ligand-based) of the unpaired extra electron of the reduced species

Electrochemical and spectroelectrochemical study of cyclometallated platinum derivatives with nitrogen ligands. Electrogeneration of monomeric reduced platinum species / Minghetti, G.; Pilo, Maria Itria; Sanna, Gavino; Seeber, R.; Stoccoro, S.; Laschi, F.. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 452:1-2(1993), pp. 257-261. [10.1016/0022-328X(93)83200-F]

Electrochemical and spectroelectrochemical study of cyclometallated platinum derivatives with nitrogen ligands. Electrogeneration of monomeric reduced platinum species

G. Minghetti;PILO, Maria Itria;SANNA, Gavino;S. Stoccoro;
1993

Abstract

The cathodic reduction of the complexes [LPtCl] and [LPtL′] (BF4) [HL 6-(1-methylbenzyl)-2,2′-bipyridine and L′ triphenylphosphine, pyridine, or acetonitrile] has been studied in acetonitrile and dichloromethane solvents. The main goal has been that of defining the nature and reactivity of the corresponding relatively stable one-electron reduced forms. In particular, X-band EPR spectrometry has allowed us to get information about the character (metal- or ligand-based) of the unpaired extra electron of the reduced species
Electrochemical and spectroelectrochemical study of cyclometallated platinum derivatives with nitrogen ligands. Electrogeneration of monomeric reduced platinum species / Minghetti, G.; Pilo, Maria Itria; Sanna, Gavino; Seeber, R.; Stoccoro, S.; Laschi, F.. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 452:1-2(1993), pp. 257-261. [10.1016/0022-328X(93)83200-F]
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11388/46906
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 13
  • ???jsp.display-item.citation.isi??? 13
social impact