A mild, efficient, metal- and solvent-free oxidation of primary amines to aldehydes, ketones, and nitriles under ball-milling conditions is presented. This method has proved to be compatible with various functional groups and only requires easily accessible starting materials. Simple purification of the reaction mixtures by short-column chromatography afforded pure aldehydes, ketones, and nitriles as products.
A Mechanochemical-Assisted Oxidation of Amines to Carbonyl Compounds and Nitriles / Gaspa, Silvia; Porcheddu, Andrea; Valentoni, Antonio; Garroni, Sebastiano; Enzo, Stefano; DE LUCA, Lidia Vera Giovanna. - In: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. - ISSN 1434-193X. - 37(2017), pp. 5519-5526. [10.1002/ejoc.201700689]
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Titolo: | A Mechanochemical-Assisted Oxidation of Amines to Carbonyl Compounds and Nitriles | |
Autori: | ||
Data di pubblicazione: | 2017 | |
Rivista: | ||
Citazione: | A Mechanochemical-Assisted Oxidation of Amines to Carbonyl Compounds and Nitriles / Gaspa, Silvia; Porcheddu, Andrea; Valentoni, Antonio; Garroni, Sebastiano; Enzo, Stefano; DE LUCA, Lidia Vera Giovanna. - In: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. - ISSN 1434-193X. - 37(2017), pp. 5519-5526. [10.1002/ejoc.201700689] | |
Handle: | http://hdl.handle.net/11388/196901 | |
Appare nelle tipologie: | 1.1 Articolo in rivista |