The copper derivative [Cu(H-stp)(bipy)(H2O)2]n·H2O (1) is afforded by combining flexible 2-sulfoterephthalic acid monosodium salt [Na(H2stp)] and divalent copper nitrate in presence of the N-donor ancillary co-ligand, 4,4’-bipyridyl. As a result of the potential coordination modes of carboxylate oxygens from the stp ligand and the bipy co-ligand, a one dimensional chain is formed as evident by single-crystal X-ray diffraction technique. Solvent exchange studies reveals that compound 1 is able to sense various small polar volatile organic compounds (VOCs) and acts as a good capacitative sensor under ambient conditions. An increase of the temperature from 100 to 298 K on EPR measurement causes a variation of the SOMO composition and a change of the spectrum from an ’inverse’ to a ‘rhombic’ one. On temperature dependent magnetic study, the cMT value of compound 1 is 6.86 cm3 K mol-1 at 5 K which decreases up to 8.81 cm3 K mol-1 at 300 K.

A New CuII Coordination Polymer: Structural Elucidation, EPR and Sensing Studies for Detection of Volatile Organic Solvents / Das, Kuheli; Mendiratta, Shruti; Datta, Amitabha; Gajewska, Małgorzata J.; Garribba, Eugenio; Akitsu, Takashiro; Sinha, Chittaranjan. - In: CHEMISTRYSELECT. - ISSN 2365-6549. - 1:10(2016), pp. 2192-2198. [10.1002/slct.201600390]

A New CuII Coordination Polymer: Structural Elucidation, EPR and Sensing Studies for Detection of Volatile Organic Solvents

GARRIBBA, Eugenio;
2016-01-01

Abstract

The copper derivative [Cu(H-stp)(bipy)(H2O)2]n·H2O (1) is afforded by combining flexible 2-sulfoterephthalic acid monosodium salt [Na(H2stp)] and divalent copper nitrate in presence of the N-donor ancillary co-ligand, 4,4’-bipyridyl. As a result of the potential coordination modes of carboxylate oxygens from the stp ligand and the bipy co-ligand, a one dimensional chain is formed as evident by single-crystal X-ray diffraction technique. Solvent exchange studies reveals that compound 1 is able to sense various small polar volatile organic compounds (VOCs) and acts as a good capacitative sensor under ambient conditions. An increase of the temperature from 100 to 298 K on EPR measurement causes a variation of the SOMO composition and a change of the spectrum from an ’inverse’ to a ‘rhombic’ one. On temperature dependent magnetic study, the cMT value of compound 1 is 6.86 cm3 K mol-1 at 5 K which decreases up to 8.81 cm3 K mol-1 at 300 K.
2016
A New CuII Coordination Polymer: Structural Elucidation, EPR and Sensing Studies for Detection of Volatile Organic Solvents / Das, Kuheli; Mendiratta, Shruti; Datta, Amitabha; Gajewska, Małgorzata J.; Garribba, Eugenio; Akitsu, Takashiro; Sinha, Chittaranjan. - In: CHEMISTRYSELECT. - ISSN 2365-6549. - 1:10(2016), pp. 2192-2198. [10.1002/slct.201600390]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11388/175728
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