The [CuPPh3CCPh]4 tetramer, obtained by treatment of [Cu(PPh3)2BH4] with phenylacetylene and KOH (molar ratio 1/1/1) in 1/1 benzene/benzyl alcohol, consists of a tetrahedral skeleton of metal atoms bonded to four terminal phosphine molecules and to four μ-3 -bridging phenylacetylide ligands which behave essentially as 2e donors. © 1985.

Synthesis and X-ray structure of [CuPPh3CCPh]4, an electron deficient molecule with μ-bridging phenylacetylide ligands / Naldini, Luciana; Demartin, Francesco; Manassero, Mario; Sansoni, Mirella; Rassu, Gloria; Zoroddu, Maria Antonietta. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 279:3(1985), pp. c42-c44. [10.1016/0022-328X(85)87051-0]

Synthesis and X-ray structure of [CuPPh3CCPh]4, an electron deficient molecule with μ-bridging phenylacetylide ligands

NALDINI, Luciana;ZORODDU, Maria Antonietta
1985

Abstract

The [CuPPh3CCPh]4 tetramer, obtained by treatment of [Cu(PPh3)2BH4] with phenylacetylene and KOH (molar ratio 1/1/1) in 1/1 benzene/benzyl alcohol, consists of a tetrahedral skeleton of metal atoms bonded to four terminal phosphine molecules and to four μ-3 -bridging phenylacetylide ligands which behave essentially as 2e donors. © 1985.
Synthesis and X-ray structure of [CuPPh3CCPh]4, an electron deficient molecule with μ-bridging phenylacetylide ligands / Naldini, Luciana; Demartin, Francesco; Manassero, Mario; Sansoni, Mirella; Rassu, Gloria; Zoroddu, Maria Antonietta. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 279:3(1985), pp. c42-c44. [10.1016/0022-328X(85)87051-0]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11388/167617
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