Dirhodium(II) complexes have been prepared from [Rh2(HNCOCF3)4] and 2,4-diamino-5-(3′,4′,5′-trimethoxybenzyl)pyrimidine(trim) or 2,4-diamino-5-(p-chlorophenyl)-6-ethylpyrimidine (pyr). Elemental analyses, electronic absorption data and magnetic roomtemperature susceptibility measurements indicate that the complexes are binuclear with the pyrimidines terminally coordinated to rhodium atoms which are bridged by the trifluoroacetamidato-cage. © 1989 Chapman and Hall Ltd.
Interactions of tetrakis-(μ-trifluoroacetamidato)-dirhodium(II) with 2,4-diaminopyrimidines / Zoroddu, Maria Antonietta; Dallocchio, Roberto. - In: TRANSITION METAL CHEMISTRY. - ISSN 0340-4285. - 14:4(1989), pp. 267-268. [10.1007/BF01098226]
Interactions of tetrakis-(μ-trifluoroacetamidato)-dirhodium(II) with 2,4-diaminopyrimidines
ZORODDU, Maria Antonietta;
1989-01-01
Abstract
Dirhodium(II) complexes have been prepared from [Rh2(HNCOCF3)4] and 2,4-diamino-5-(3′,4′,5′-trimethoxybenzyl)pyrimidine(trim) or 2,4-diamino-5-(p-chlorophenyl)-6-ethylpyrimidine (pyr). Elemental analyses, electronic absorption data and magnetic roomtemperature susceptibility measurements indicate that the complexes are binuclear with the pyrimidines terminally coordinated to rhodium atoms which are bridged by the trifluoroacetamidato-cage. © 1989 Chapman and Hall Ltd.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
