Heterobimetallic complexes with metal centers connected by a small delocalized ligand constitute an interesting class of compounds. Here we report that starting from the mononuclear platinum(II) rollover complexes [Pt(bipy-H)(L)Cl] (bipy-H = 2,2′-bipyridine C(3′)-N cyclometalated, L= DMSO, PPh 3) a second rollover cyclometalation may produce a series of Pt(II)/Pd(II) heterobimetallic complexes where the two metals are linked by the planar, highly delocalized, doubly deprotonated 2,2′-bipyridine

Heterobimetallic rollover derivatives / Petretto, Giacomo L.; Rourke, Jonathan P.; Maidich, Luca; Stoccoro, Sergio; Cinellu, Maria Agostina; Minghetti, Giovanni; Clarkson, Guy J.; Zucca, Antonio. - In: ORGANOMETALLICS. - ISSN 0276-7333. - 31:8(2012), pp. 2971-2977. [10.1021/om200660a]

Heterobimetallic rollover derivatives

Petretto, Giacomo L.;Maidich, Luca;Stoccoro, Sergio;Cinellu, Maria Agostina;Minghetti, Giovanni;Zucca, Antonio
2012

Abstract

Heterobimetallic complexes with metal centers connected by a small delocalized ligand constitute an interesting class of compounds. Here we report that starting from the mononuclear platinum(II) rollover complexes [Pt(bipy-H)(L)Cl] (bipy-H = 2,2′-bipyridine C(3′)-N cyclometalated, L= DMSO, PPh 3) a second rollover cyclometalation may produce a series of Pt(II)/Pd(II) heterobimetallic complexes where the two metals are linked by the planar, highly delocalized, doubly deprotonated 2,2′-bipyridine
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11388/155625
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