Reductive cleavage of open chain and cyclic alpha-N,N-dialkylamino-substituted benzyl alkyl ethers 1a-f with a dispersion of Li metal and a catalytic amount of naphthalene in THF, allowed easy access to a wide array of alpha-N,N-dialkylamino-substituted benzyllithium derivatives. Reaction of these organometallics with various electrophiles afforded the expected products in satisfactory yields

Generation and Reactivity of a-Amino-Substituted Arylmethyllithium Organometallics / Azzena, Ugo Gavino; Luciano, Pilo; Elisabetta, Piras. - In: TETRAHEDRON. - ISSN 0040-4020. - 56:(2000), pp. 3775-3780. [10.1016/S0040-4020(00)00303-3]

Generation and Reactivity of a-Amino-Substituted Arylmethyllithium Organometallics

AZZENA, Ugo Gavino;
2000-01-01

Abstract

Reductive cleavage of open chain and cyclic alpha-N,N-dialkylamino-substituted benzyl alkyl ethers 1a-f with a dispersion of Li metal and a catalytic amount of naphthalene in THF, allowed easy access to a wide array of alpha-N,N-dialkylamino-substituted benzyllithium derivatives. Reaction of these organometallics with various electrophiles afforded the expected products in satisfactory yields
2000
Generation and Reactivity of a-Amino-Substituted Arylmethyllithium Organometallics / Azzena, Ugo Gavino; Luciano, Pilo; Elisabetta, Piras. - In: TETRAHEDRON. - ISSN 0040-4020. - 56:(2000), pp. 3775-3780. [10.1016/S0040-4020(00)00303-3]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11388/83765
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