The importance of electrostatic effects in the chemical evolution of charged intermediates of the radical anion type is demonstrated, Thus, the regioselectivity of the electron transfer-induced reductive cleavage of alkyl 2,6-diphenylphenyl ethers and alkyl 2,6-dimethoxyphenyl ethers is completely reversed when a positive charge is placed in a controlled manner near the alkyl ether bond

The Effect of Topologically Controlled Coulombic Interactions on the Regioselectivity of the Reductive Cleavage of Alkyl Phenyl Ethers / Azzena, Ugo Gavino; F., Casado; P., Fois; I., Gallardo; Pisano, Luisa; J., Marquet; G., Melloni. - In: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS II. - ISSN 0300-9580. - 12(1996), pp. 2563-2566. [10.1039/p29960002563]

The Effect of Topologically Controlled Coulombic Interactions on the Regioselectivity of the Reductive Cleavage of Alkyl Phenyl Ethers

AZZENA, Ugo Gavino;PISANO, Luisa;
1996-01-01

Abstract

The importance of electrostatic effects in the chemical evolution of charged intermediates of the radical anion type is demonstrated, Thus, the regioselectivity of the electron transfer-induced reductive cleavage of alkyl 2,6-diphenylphenyl ethers and alkyl 2,6-dimethoxyphenyl ethers is completely reversed when a positive charge is placed in a controlled manner near the alkyl ether bond
1996
The Effect of Topologically Controlled Coulombic Interactions on the Regioselectivity of the Reductive Cleavage of Alkyl Phenyl Ethers / Azzena, Ugo Gavino; F., Casado; P., Fois; I., Gallardo; Pisano, Luisa; J., Marquet; G., Melloni. - In: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS II. - ISSN 0300-9580. - 12(1996), pp. 2563-2566. [10.1039/p29960002563]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11388/47203
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