We investigated the reducing properties of a series of 1,2-diaryl-1,2-disodiumethanes by means of equilibration reactions. The electron-donor power of these vic-diorganometals is strongly affected by the nature of substituents present either on the aromatic ring(s) or on the carbanionic centers, and it can be correlated with their ability to delocalize the arylmethyl carbanions. These findings are supported by electrochemical analysis of the reduction behavior of the parent 1,2-diarylalkene. Applications of these results to the reduction of selected substrates are described

Tuning the Reducing Properties of 1,2-Diaryl-1,2-disodiumethanes / Azzena, U; Pisano, L; Antonello, S; Maran, F. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - 74:21(2009), pp. 8064-8070. [10.1021/jo901183x]

Tuning the Reducing Properties of 1,2-Diaryl-1,2-disodiumethanes

AZZENA, U;PISANO, L;
2009-01-01

Abstract

We investigated the reducing properties of a series of 1,2-diaryl-1,2-disodiumethanes by means of equilibration reactions. The electron-donor power of these vic-diorganometals is strongly affected by the nature of substituents present either on the aromatic ring(s) or on the carbanionic centers, and it can be correlated with their ability to delocalize the arylmethyl carbanions. These findings are supported by electrochemical analysis of the reduction behavior of the parent 1,2-diarylalkene. Applications of these results to the reduction of selected substrates are described
2009
Tuning the Reducing Properties of 1,2-Diaryl-1,2-disodiumethanes / Azzena, U; Pisano, L; Antonello, S; Maran, F. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - 74:21(2009), pp. 8064-8070. [10.1021/jo901183x]
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11388/45183
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 18
  • ???jsp.display-item.citation.isi??? 18
social impact