A new photocatalyzed route to amides from alcohols and amines mediated by visible light is presented. The reaction is carried out in ethyl acetate as a solvent. Ethyl acetate can be defined a green and bio-based solvent. The starting materials such as the energy source are easily available, stable, and inexpensive. The reaction has shown to be general and high yielding.
Visible-Light Photoredox-Catalyzed Amidation of Benzylic Alcohols / Gaspa, S.; Farina, A.; Tilocca, M.; Porcheddu, A.; Pisano, L.; Carraro, M.; Azzena, U.; De Luca, L.. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - 85:18(2020), pp. 11679-11687. [10.1021/acs.joc.0c01320]
Visible-Light Photoredox-Catalyzed Amidation of Benzylic Alcohols
Gaspa S.;Farina A.;Tilocca M.;Porcheddu A.;Pisano L.;Carraro M.;Azzena U.;De Luca L.
2020-01-01
Abstract
A new photocatalyzed route to amides from alcohols and amines mediated by visible light is presented. The reaction is carried out in ethyl acetate as a solvent. Ethyl acetate can be defined a green and bio-based solvent. The starting materials such as the energy source are easily available, stable, and inexpensive. The reaction has shown to be general and high yielding.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
