The reaction of [Cu2(O2CCH3)4·2H2O] with trimethoprim is reported. In methanol a green solution was obtained, which, on adding benzene, yielded tetrakis(μ-acetato)bis(trimethoprim)dicopper(II) di-benzene methanol solvate. The compound crystallizes with four molecules per cell in the monoclinic space group C2/c, with a = 24.109(5), b = 15.256(3), c = 16.532(3) Å, β = 116.89(2) for λ(Mo-Kα) = 0.71073 Å. The copper atoms are bridged by four acetate groups to form the binuclear molecule [Cu2-(O2CCH3)4(TMP)2]·2C6H6·CH3OH. The TMP ligand acts as a donor molecule through one pyrimidinic nitrogen atom. © 1984.
Metal complexes of 2,4-diamino-5-(3′,4′,5′-trimethoxybenzyl)pyrimidine, (trimethoprim). Part II. Synthesis, magnetic characterization and X-ray structure of [Cu2(O2CCH3)4(trimethoprim)2]·2C6H6·CH3OH / Naldini, Luciana; Cabras, Maria Antonietta; Zoroddu, Maria Antonietta; Demartin, Francesco; Manassero, Mario; Sansoni, Mirella. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - 88:1(1984), pp. 45-50. [10.1016/S0020-1693(00)81869-1]
Metal complexes of 2,4-diamino-5-(3′,4′,5′-trimethoxybenzyl)pyrimidine, (trimethoprim). Part II. Synthesis, magnetic characterization and X-ray structure of [Cu2(O2CCH3)4(trimethoprim)2]·2C6H6·CH3OH
NALDINI, Luciana;CABRAS, Maria Antonietta;ZORODDU, Maria Antonietta;
1984-01-01
Abstract
The reaction of [Cu2(O2CCH3)4·2H2O] with trimethoprim is reported. In methanol a green solution was obtained, which, on adding benzene, yielded tetrakis(μ-acetato)bis(trimethoprim)dicopper(II) di-benzene methanol solvate. The compound crystallizes with four molecules per cell in the monoclinic space group C2/c, with a = 24.109(5), b = 15.256(3), c = 16.532(3) Å, β = 116.89(2) for λ(Mo-Kα) = 0.71073 Å. The copper atoms are bridged by four acetate groups to form the binuclear molecule [Cu2-(O2CCH3)4(TMP)2]·2C6H6·CH3OH. The TMP ligand acts as a donor molecule through one pyrimidinic nitrogen atom. © 1984.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
